[Octopus-users] question about core corrections

Luis Filipe Matos lfilipe at teor.fis.uc.pt
Thu Jun 1 17:11:53 WEST 2006


Hello,

I was doing some calculations with Cd and was trying to see what was the 
difference when I put the core corrections to the separation of the Vxc. 
I tried it on the dimer Cd2, but I saw that the energy doesnt' have a 
minimum as I approximate the atoms. One thing that I don't know if it's 
normal is that the exchange and correlation have huge values compared 
with the other ones, so that the total energy is mostly exchange and 
correlation.
I'm using version 2.0.1devel, with 
   
    (latest cvs changes: 2006/03/13 13:34:50 v_ks_inc.F90,v 1.19)

                           Compiler: ifort
                Compiler flags: -zero -nbs -r8 -ip -O0

luis
-------------- next part --------------
SystemName = "Cd2"
CalculationMode = gs
Units = "a.u."
FromScratch = yes

BoxShape = cylinder
Radius  = 15.0
Spacing = 0.4
Xlength = 12.00000

%Species
"Cd" | 112.4110000  | tm2 | 48 | 2 | 0
%

%Coordinates
"Cd" |  2.00000  | 0.0 | 0
"Cd" | -2.00000  | 0.0 | 0
%

%Occupations
2 | 2 
%



XFunctional = lda_x
CFunctional = lda_c_pw



MaximumIter = 200 #número máximo de iterações no ciclo de auto-convergência
ConvRelDens = 1e-6 #critério de convergência (default=densidade)

LCAOStart = yes

EigenSolver = cg_new #maneira de resolver os mínimos
EigenSolverInitTolerance = 1e-4
EigenSolverFinalTolerance = 1e-8
EigenSolverFinalToleranceIteration = 6
EigenSolverMaxIter = 1000 #número de ciclos máximo dentro de cada iteração do ciclo de autoconsistência
TypeOfMixing = broyden

Output = potential + density + wfs
OutputHow = plane_x + plane_y
OutputEvery = 1
OutputDuringSCF = yes
OutputWfsNumber = "1-2"



-------------- next part --------------
 Cd pw nrl pcec
 APE Version-0.7.1   2006/05/29   Hamann                     
 1s 1.90  r= 1.20/2p 0.05  r= 1.70/3d 0.05  r= 3.60/                   
   3  0 1200        0.0081601583        0.0084544407        2.0000000000
 Radial grid follows
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   1.48942476638       1.51558479436       1.54219493335       1.56926276745    
   1.59679600344       1.62480247258       1.65329013237       1.68226706832    
   1.71174149582       1.74172176190       1.77221634710       1.80323386731    
   1.83478307561       1.86687286419       1.89951226616       1.93271045750    
   1.96647675891       2.00082063777       2.03575171000       2.07127974200    
   2.10741465258       2.14416651488       2.18154555828       2.21956217037    
   2.25822689884       2.29755045342       2.33754370781       2.37821770159    
   2.41958364212       2.46165290646       2.50443704325       2.54794777461    
   2.59219699794       2.63719678784       2.68295939788       2.72949726243    
   2.77682299843       2.82494940713       2.87388947579       2.92365637943    
   2.97426348237       3.02572433994       3.07805269995       3.13126250425    
   3.18536789016       3.24038319191       3.29632294190       3.35320187203    
   3.41103491490       3.46983720490       3.52962407924       3.59041107897    
   3.65221394975       3.71504864268       3.77893131490       3.84387833016    
   3.90990625923       3.97703188016       4.04527217849       4.11464434722    
   4.18516578667       4.25685410419       4.32972711369       4.40380283494    
   4.47909949279       4.55563551610       4.63342953645       4.71250038669    
   4.79286709926       4.87454890413       4.95756522665       5.04193568507    
   5.12768008765       5.21481842967       5.30337088999       5.39335782732    
   5.48479977604       5.57771744190       5.67213169705       5.76806357479    
   5.86553426398       5.96456510289       6.06517757255       6.16739328976    
   6.27123399958       6.37672156705       6.48387796862       6.59272528305    
   6.70328568135       6.81558141632       6.92963481168       7.04546824998    
   7.16310416001       7.28256500385       7.40387326259       7.52705142124    
   7.65212195342       7.77910730465       7.90802987449       8.03891199836    
   8.17177592834       8.30664381204       8.44353767126       8.58247937987    
   8.72349063923       8.86659295311       9.01180760235       9.15915561647    
   9.30865774448       9.46033442563       9.61420575718       9.77029146040    
   9.92861084695       10.0891827825       10.2520256474       10.4171572981    
   10.5845950262       10.7543555135       10.9264547873       11.1009081752    
   11.2777302535       11.4569347960       11.6385347237       11.8225420464    
   12.0089678045       12.1978220122       12.3891135931       12.5828503133    
   12.7790387176       12.9776840591       13.1787902230       13.3823596546    
   13.5883932824       13.7968904332       14.0078487492       14.2212641064    
   14.4371305184       14.6554400441       14.8761826981       15.0993463462    
   15.3249166001       15.5528767209       15.7832075055       16.0158871689    
   16.2508912380       16.4881924311       16.7277605267       16.9695622461    
   17.2135611275       17.4597173811       17.7079877591       17.9583254254    
   18.2106797977       18.4649964036       18.7212167463       18.9792781363    
   19.2391135317       19.5006514007       19.7638155448       20.0285249250    
   20.2946935173       20.5622301353       20.8310382399       21.1010157884    
   21.3720550605       21.6440424542       21.9168583266       22.1903768297    
   22.4644656955       22.7389860671       23.0137923510       23.2887319961    
   23.5636453165       23.8383653631       24.1127177064       24.3865202538    
   24.6595831401       24.9317085302       25.2026904324       25.4723146097    
   25.7403584182       26.0065906230       26.2707713301       26.5326518800    
   26.7919746740       27.0484731298       27.3018716484       27.5518854634    
   27.7982206270       28.0405740637       28.2786334654       28.5120773142    
   28.7405750355       28.9637869670       29.1813644303       29.3929499912    
   29.5981775387       29.7966724220       29.9880518222       30.1719249848    
   30.3478934394       30.5155514939       30.6744866592       30.8242799791    
   30.9645066596       31.0947367210       31.2145354744       31.3234643032    
   31.4210815712       31.5069432894       31.5806040745       31.6416183303    
   31.6895411572       31.7239295189       31.7443437015       31.7503485257    
   31.7415147523       31.7174208242       31.6776544265       31.6218141699    
   31.5495116190       31.4603732251       31.3540423263       31.2301814719    
   31.0884747150       30.9286299697       30.7503816391       30.5534932171    
   30.3377600237       30.1030121468       29.8491172535       29.5759836905    
   29.2835637368       28.9718564884       28.6409112322       28.2908309870    
   27.9217752979       27.5339636616       27.1276793025       26.7032716840    
   26.2611595860       25.8018350044       25.3258651486       24.8338945538    
   24.3266488802       23.8049361170       23.2696468514       22.7217575576    
   22.1623306394       21.5925117118       21.0135316451       20.4267049395    
   19.8334226338       19.2351518470       18.6334317438       18.0298605370    
   17.4260904273       16.8238201564       16.2247743649       15.6306907718    
   15.0433079240       14.4643348471       13.8954260998       13.3381626221    
   12.7940092081       12.2642719224       11.7500681594       11.2522690690    
   10.7714366684       10.3077644672       9.86104622672       9.43083472513    
   9.01662072617       8.61791692197       8.23425248852       7.86516224436    
   7.51018822995       7.16889178355       6.84084208956       6.52561324810    
   6.22279688019       5.93199428012       5.65281078137       5.38486674101    
   5.12779370925       4.88122685498       4.64481376493       4.41821436492    
   4.20109217062       3.99312071098       3.79398642288       3.60337955755    
   3.42099833233       3.24655393857       3.07976180724       2.92034366731    
   2.76803376861       2.62257117978       2.48370004617       2.35117609450    
   2.22476056664       2.10421894832       1.98932706530       1.87986690911    
   1.77562414008       1.67639340692       1.58197616439       1.49217722157    
   1.40680893953       1.32569085887       1.24864575437       1.17550276712    
   1.10609835955       1.04027218962      0.977869188692      0.918741540104    
  0.862744716652      0.809738597400      0.759589979924      0.712169067165    
  0.667349786717      0.625012499725      0.585041131223      0.547322812994    
  0.511750454591      0.478220675098      0.446632932167      0.416891784015    
  0.388905570584      0.362585173255      0.337845866198      0.314606765450    
  0.292789335797      0.272318738922      0.253123922040      0.235136037343    
  0.218289343620      0.202521727231      0.187773166800      0.173986249571    
  0.161106943439      0.149083218623      0.137865247961      0.127406268134    
  0.117661440522      0.108587802717      0.100145095041      0.922949105913E-01
  0.850004538712E-01  0.782272581885E-01  0.719426268342E-01  0.661152588106E-01
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  0.102508018722E-02  0.908268133484E-03  0.803939160868E-03  0.710847836150E-03
  0.627876057157E-03  0.554004889608E-03  0.488300109267E-03  0.429924171338E-03
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  0.223757123644E-03  0.195701712370E-03  0.170970574029E-03  0.149193206601E-03
  0.130038003988E-03  0.113210977214E-03  0.984457169949E-04  0.855038004714E-04
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  0.415027702972E-04  0.357839676287E-04  0.308146544544E-04  0.265021858636E-04
  0.227639094723E-04  0.195278659720E-04  0.167303896092E-04  0.143147975132E-04
  0.122318386165E-04  0.104382787146E-04  0.889572461007E-05  0.757085764437E-05
  0.643466641479E-05  0.546147126557E-05  0.462900856011E-05  0.391804637847E-05
  0.331162598336E-05  0.279505693223E-05  0.235574615733E-05  0.198263990137E-05
  0.166617142904E-05  0.139819600614E-05  0.117160427616E-05  0.980251771264E-06
  0.818936373355E-06  0.683146407279E-06  0.568989495709E-06  0.473186628270E-06
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  0.838503044449E-07  0.686234230217E-07  0.560668053962E-07  0.457291195645E-07
  0.372353695632E-07  0.302670418440E-07  0.245592278078E-07  0.198937794237E-07
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  0.556651659805E-10  0.428601132850E-10  0.329254689468E-10  0.252402507780E-10
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  0.646107749970E-11  0.488619724034E-11  0.368696328202E-11  0.277517764521E-11
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  0.239406561230E-15  0.169835659115E-15  0.120559638567E-15  0.444607955979E-16
 -0.879266252958E-17 -0.200162059854E-17  0.246219072790E-17 -0.747810755789E-18
 -0.919585880706E-19  0.177638865899E-18 -0.618201719173E-19 -0.251206722571E-20
  0.125902550287E-19 -0.499590159791E-20  0.131956139893E-21  0.874445702271E-21
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  0.406979934586E-23  0.390267765450E-23 -0.237001394952E-23  0.418026257519E-24
  0.247062469093E-24 -0.179232988553E-24  0.391381546995E-25  0.148055389217E-25
 -0.133568436216E-25   0.00000000000       0.00000000000       0.00000000000    
   0.00000000000       0.00000000000       0.00000000000       0.00000000000    
   0.00000000000       0.00000000000       0.00000000000       0.00000000000    
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   0.00000000000       0.00000000000       0.00000000000       0.00000000000    
   0.00000000000       0.00000000000       0.00000000000       0.00000000000    
 Valence charge follows
  0.958595605343E-10  0.386700655285E-09  0.877489826923E-09  0.157329226443E-08
  0.247927360469E-08  0.360070176587E-08  0.494294881309E-08  0.651149285708E-08
  0.831191998618E-08  0.103499262325E-07  0.126313195726E-07  0.151620219637E-07
  0.179480714150E-07  0.209956240967E-07  0.243109564848E-07  0.279004675448E-07
  0.317706809528E-07  0.359282473567E-07  0.403799466762E-07  0.451326904439E-07
  0.501935241874E-07  0.555696298529E-07  0.612683282722E-07  0.672970816719E-07
  0.736634962281E-07  0.803753246645E-07  0.874404688972E-07  0.948669827255E-07
  0.102663074570E-06  0.110837110258E-06  0.119397615861E-06  0.128353280575E-06
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  0.179374905860E-06  0.190893509940E-06  0.202872918250E-06  0.215323235119E-06
  0.228254756353E-06  0.241677972665E-06  0.255603573170E-06  0.270042448937E-06
  0.285005696608E-06  0.300504622072E-06  0.316550744213E-06  0.333155798717E-06
  0.350331741948E-06  0.368090754893E-06  0.386445247172E-06  0.405407861124E-06
  0.424991475959E-06  0.445209211987E-06  0.466074434916E-06  0.487600760233E-06
  0.509802057650E-06  0.532692455641E-06  0.556286346049E-06  0.580598388777E-06
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  0.834281489170E-06  0.866643845173E-06  0.899904730890E-06  0.934082420138E-06
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  0.167481127822E-05  0.172903114468E-05  0.178458640711E-05  0.184150334462E-05
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  0.271820235313E-05  0.279722617969E-05  0.287806832838E-05  0.296076383992E-05
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  0.340331322374E-05  0.349790102198E-05  0.359460583805E-05  0.369346810239E-05
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