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Origin of the optical contrast in phase change materials

Authors: W. Welnic, S. Botti, L. Reining, and M. Wuttig

Ref.: Phys. Rev. Lett. 98, 236403 (2007)

Abstract: Several chalcogenide alloys exhibit a pronounced contrast between the optical absorption in the metastable rocksalt and in the amorphous phase. This phenomenon is the basis for their application in optical data storage. Here we present ab initio calculations of the optical properties of GeTe and Ge1Sb2Te4 in the two phases. The analysis of our computations and experimental data reveal the correlation between local structural changes and optical properties as well as the origin of the optical contrast in these materials. We find that the change in optical properties cannot be attributed to a smearing of transition energies as commonly assumed for amorphous semiconductors: the optical contrast between the two phases can only be explained by significant changes in the transition matrix elements.

Citations: 128 (Google scholar)

DOI: 10.1103/PhysRevLett.98.236403

URL: link.aps.org

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Bibtex:

@article{We_nic_2007,
	doi = {10.1103/physrevlett.98.236403},
	url = {https://doi.org/10.1103%2Fphysrevlett.98.236403},
	year = 2007,
	month = {jun},
	publisher = {American Physical Society ({APS})},
	volume = {98},
	number = {23},
	author = {Wojciech We{\l}nic and Silvana Botti and Lucia Reining and Matthias Wuttig},
	title = {Origin of the Optical Contrast in Phase-Change Materials},
	journal = {Physical Review Letters}
}